Everything posted by exchemist
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Decontamination of metals
I think you can get drain cleaner which is based on strong acids (some is also based on strong alkali), but I hesitate to suggest you try, as they are fairly nasty if you spill them on you - or anything else. Citric acid has a first pKa of 3.1 whereas acetic acid has a pKa of 4.76, so citric acid is a bit stronger but not much. (For comparison a strong acid such as HCl has a pKa of -6, so in a different ballpark entirely).
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Decontamination of metals
I used the term Ac a bit wrongly actually. Ac, strictly denotes the acetyl group, which is CH3CO - so I should have said Mg(OAc)₂. I'm retired and very out of practice, I'm afraid. Probably best to refer to it as Mg (CH3COO)₂ , to avoid getting into a nomenclature minefield. Regarding Zn's apparent low reactivity, acetic acid is a weak acid. At molar concentration (similar to vinegar), only about 0.4% is dissociated into H+ and acetate. If you had a molar strong acid, e.g. HCl, the reaction would be more obvious I think.
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Electron shells
Electrons in atoms can be thought of as standing waves corresponding to resonant frequencies, ie. a series of harmonics. In fact the shapes of atomic orbitals are spherical harmonics, akin to the modes of vibration of a rubber ball if you hit it and look at how it vibrates with a strobe light. Each electron occupies a different quantum state. It has to, as electrons are fermions. "Shells" are simply groupings of related, but different states that are possible for an electron to occupy in an atom. Each shell comprises all the states that have the same principal quantum number, n. But n is only one of 4 quantum numbers needed to specify individual possible states. They others are: - l, which denotes the angular momentum and determines which subshell the electron is in (i.e. s, p, d, f etc), - m(l), which determines which member of the sets of s, p,d, f orbitals the electron is in (e.g p(z), d(x²-y²), etc), - and finally m(s) which determines the spin orientation within that orbital. So one can have a maximum of 2 electrons per orbital, one with spin orientation "up" and the other "down". In chemistry, this accounts for the pattern of the Periodic Table of the elements, each row corresponding to the highest occupied principal shell that is occupied, 1st row n=1 2nd row n=2 etc. (cf. Aufbau Principle.)
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How long can a tetanus shot protect you?
10 years is the general practice in the UK, certainly, though it is not recommended that everyone needs it. I used to get it topped up when I travelled abroad with Shell, as it was company policy, but not any more. If I worked with horses, or as a gardener, that would be different.
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calcium carbonate decomposition temperature
So, answering the actual, actual question😃, since MW of CaCO3 is 40+12 + (16x3) = 100, 2g would absorb 2/100 x 177.8 = 3.556kJ, wouldn't it?
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Got COVID, should I take anything?
Get yourself topped up with a booster. You'll have to wait a bit, seeing as you've just been infected, but keeping your booster immunisations up to date as per medical advice is by far the best thing you can do. Even then you can still expect to get covid from time to time, but far less badly unless you have some underlying condition. There is no need for anything to deal with the infection you have now, so long as symptoms remain mild. But from my own experience (I caught the original version before any vaccines were available, and lost my sense of taste and smell for several weeks) I would advise being careful how quickly you return to full normal activities, as it can leave you fatigued for a few weeks. Do not attempt to fight through any fatigue you may experience or it will slow down your recovery.
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Color reactions of Amino Acids
Hmm. I suspect that will be to do with the tendency of amino acids to exist as zwitterions. I don't think you can rely on an acid/base colour indicator to work, because of the basicity of the amine end. So you would have to find reactions that bind carboxylate specifically and thereby produce a colour change. Perhaps something involving a transition metal ion, for which RCOO- could be a coordination ligand?
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Color reactions of Amino Acids
Ah yes, probably. Let's see if our poster can take part in a conversation about this.
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Color reactions of Amino Acids
What reaction are you talking about?
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Decontamination of metals
OK have fun. Try it with zinc too - I'm a bit surprised you saw no reaction. By the way, I should have said Mg(Ac)₂ of course.
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Decontamination of metals
You might want to brush up on the Electrochemical Series. That tells you which metals are expected to react with acids to liberate hydrogen (basically anything with an electrode potential that is -ve relative to hydrogen, which is set at zero by convention.) An example here: https://chemguide.co.uk/physical/redoxeqia/ecs.html According to this, Mg is expected to react, and Cu is not. Zn however is slightly -ve, so would be expected to react, but not as vigorously as Mg. But there may be a protective oxide layer that interferes - I can't remember. The reaction product with Mg should indeed be MgAc. If the Mg strip has an oxide layer, I should think rubbing with wire wool (i.e. a scouring pad without soap impregnation) would be one way to get that off. Other, less ancient, chemists may be able to add to this or correct it......
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How does the light from distant stars get to our eyes?
I think this will just add confusion for our questioner, quite honestly. We have not been talking about the double slit experiment but about light reaching us from stars. All the stuff about the principle of least time etc. notwithstanding, nothing about the current QM model suggests that light quanta do not travel, for all practical purposes, in a specific direction, nor that their associated waves do not have a direction of propagation, even if it is only, strictly, a predominant one. The idea our questioner has, that a single photon has a wave that spreads out uniformly in all directions, is not correct and we need to make that clear, I think.
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How does the light from distant stars get to our eyes?
There is one big misunderstanding here, which is to think each photon spreads out in all directions. It doesn’t. An individual photon is emitted in a particular direction. So the issue of something behind the emitter absorbing the wave before it gets to you does not arise.
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Schrodingers cat question
According to my (limited) understanding of Rovelli's relational interpretation, the wave function applicable from the cat's perspective is different from the wave function applicable from our perspective, so long as the box remains closed. There is not necessarily a single, absolute, wave function describing a quantum system: it depends on the informational state to which it relates. The cat, being inside the box , is in a different informational state from those outside and so a different wave function applies, from its perspective.
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The Double Slit Experiment Reexplained.
By being out of phase. Nothing to do with charge. What nonsense. The same wave (i.e. a single excitation) passing though 2 slits will form an interference pattern on the far side. This is basic.
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Question about evolution
Er, well, mastodons, sabre-toothed tigers, etc. appeared about 40m or more years later, from the Miocene onwards. The mammals that existed at the end of the Cretaceous were indeed small and shrew-like.
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Boiling chestnuts...
I have no experience with boiling chestnuts, as I usually grill them in their shells. I know that some things intrinsically tend to cook more evenly than others, though. Jerusalem artichokes (topinambours in French, aardpeeren in Dutch) are a bastard, some being still hard by the time others are disintegrating. Maybe chestnuts are like that. I suspect a (continental) cookery website will be the best place for advice.
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A wave of what? (split from How does the light from distant stars get to our eyes?)
You are attributing to me something said by @Airbrush
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A wave of what? (split from How does the light from distant stars get to our eyes?)
Waves of alternating electric and magnetic fields, at right angles to one another and to the direction of propagation. Pictures, and explanations, of this can be found in many places, for instance here: https://en.wikipedia.org/wiki/Electromagnetic_radiation
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Is carbonyl reduction irreversible?
I don't know this book but I imagine it may mean that the specific reduction reaction he is talking about has a negligible reverse rate. He can't mean alcohols cannot be oxidised to aldehydes or ketones, obviously. (I presume that, in this reaction, the leaving group in question may be hydride or something.)
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Weather balloon 1, UFO 0
OK so this was a disc-shaped radar reflector suspended from a balloon, which nevertheless prompted press reports of flying saucers. I see.
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On the lab leak theory
The probability of a new zoonotic disease being found at a random place is whatever it is. Whether there is a virus lab there or not has no effect on that probability, any more than finding it in a place with a river, or a place where the buses are red. Monkey and typewriters is a complete non-analogy as far as this is concerned.
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What is the speed of electric current?
Think of a long railway train. A locomotive starts to pull one end. The far end starts moving almost instantly, even though the speed of the train is very slow. So a signal can be transmitted very fast, even though the medium transmitting it moves slowly.
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latent heat of boiling water
When you put your hand near what you may think is steam, it is just condensed water droplets. For real steam, i.e. vapour at 100C, you would need to put your hand into the invisible stream issuing from the spout of a vigorously boiling kettle, i.e. the inch or so before it becomes visible as a cloud of "steam". If you ever do that, you will scream and need to see a doctor: the scald will be far more intense than from boiling water. Do not try it. That's because of the latent heat.
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On the lab leak theory
No it isn’t.