Changed something there, hope you don't mind.
So how does that differ from what I said? Eventually receptor affinity is determined by shape (and charge, polarisation, ...)
I never argued that smell wasn't important, and I feel sorry for e.g. people with Kallmann syndrome. Yet, at the moment it is - in my most humble opinion - quite indisputable that the way by which the composition of matter by using the periodic table is studied is less diverse (at the moment), more understandable and more important for lots of disciplines: chemistry, physics, pharmacy, medicine, biology, ...
There are some more than a hundred elements in the periodic table - there would be hundreds, thousands of different scent particles contributing to a single scent in a more or less way in an olfactory table. Working with it would be impractical, and making it would not be cost-effective.
By the way, I found the way you would set up such table rather ambiguous: please describe the "chemical" smell you try to illustrate? If I were to hang my nose above a glass of wather dissolving an effervescent tablet, I'd also describe it as "chemical".