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John Cuthber

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Posts posted by John Cuthber

  1. 4 hours ago, Sensei said:

    When you distill something, you must slightly exceed the boiling point of the substance. Check the ethanol chart, and you will have the answer to your question..

    The real question is why they think you can boil something at 120 F.

    That, together with the impossible yield and the nutrient poor recipe, suggests to me that you should not seek guidance from that site.

  2. About 95% of the population don't live in the USA.
    In the UK I can make pretty much as much wine and beer as I want, but I can't legally distill (including "freeze distillation") or sell it.
    So, I can tell you that the recipe needs nitrogen and phosphorus.
    Diammonium phosphate is traditional.
    I can also tell you (because I'm a scientist) that anyone who thinks you get 9 jars of "moonshine" from a gallon of sugar and bread-yeast is either nuts or has a very weak drink.
     

  3. 22 hours ago, ivanginato23 said:

    Does the instruction given right above (the bold one) produces the sodium cholate solution?

    No.

    Sodium cholate is not an enzyme.

    In principle, you can obtain the cholic acid from bile- if you can get that.

     

  4. Estimates vary but the current approval rating of the government is about 20%.
    The government is opposing a general election on the basis that the population would kick them out.
     

     That's not democratic.
    There's also the underlying problem; the current government was elected even though most voters preferred a different party.

    We need a new electoral system to replace "first past the post".

  5. On 10/11/2022 at 2:16 AM, TheVat said:

    A lot of call for trumpets at funerals? I'm intrigued.

     

    People would pay me not to play.

    It's interesting. I recognise the desire to teach kids the value of work.
    But, if you pay them to do chores, you undermine the idea that they should do them simply because they need to be done. 

  6. I'm not saying it's a good idea but...

    If you use solar power to drive the cooler then the heat (including the waste heat from the electrics etc) is exactly the same as if the sunlight just warmed up thee ground.
    The conservation of energy leads to the question "how could it be different?".

     

    20 hours ago, Sensei said:

    I advise you to calculate the volume of water, calculate the energy needed to lower the temperature, calculate possible energy harvested per device (not just peak maximum), and calculate the number of devices that will be needed.

    I realise the temperature of lakes will go up more or less in line with global warming.
    But is there any reason to believe that the lakes are particularly susceptible?
    Why focus on cooling lakes rather than, for example, cooling fields?

  7. On 9/19/2022 at 6:53 PM, ferrocene2 said:

    K. Goralevich said that iron tetroxide, or perferric anhydride, FeO4, or perferric acid, H2FeO5, is probably formed as a volatile, unstable compound when barium perferrate, BaFeO5, is treated with an excess of dil. sulphuric acid, at a low temp.

    Where does one get the BaFeO5 from?
    It's hard enough to get 

    https://en.wikipedia.org/wiki/Barium_ferrate
    And someone is suggesting taking another couple of electrons of the iron.

    I don't doubt the existence of Fe 8+ ions in the sun, but I don't imagine they have any chemistry.

    Much as I like reading old textbooks, I don't always accept their claims at face value.
    The difficulty with doing analysis to determine the oxidation state of the iron would be great today and I simply don't think they would have been able to guarantee accuracy back then. (This might be one of the examples of Mossbauer spectroscopy actually being useful.)


    Certainly the WIKI page doesn't say anything about Fe(VIII)
    https://en.wikipedia.org/wiki/High-valent_iron

    55 minutes ago, ferrocene2 said:

    I well remember Cotton and Wilkinson although I no longer have a copy. Were they aware, I wonder, of Fe (-II) and Fe (0)?

     

    They were. I have a copy from 1962. It mentions the carbonyl complexes as examples.

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