Everything posted by exchemist
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Arrangement of Valence electrons
Does it matter? Neither picture is anything like the actual physical arrangement, after all. It’s just a diagram to convey the idea of shells. It does not tell you anything about the real distribution of the electrons in space. (By the way there is something wrong with the atoms, or ions, in your picture. Neither has the right number of electrons.)
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Probability amplitudes,coeffecients and wave function collapse.
There is nothing in QM to suggest observation by a conscious or intelligent observer has anything to do with it. The popular misconception to the contrary is a result of the language used by the developers of the theory in the early days, which talked in terms of observable properties and hence of observers making observations. Pauli, for one, made it clear that “observation” referred just to interaction with the inanimate measuring apparatus employed in the measurement.
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Good news everybody, climate change is over!
So presumably measures to reduce CO2 emission will continue to be implemented in the more enlightened states at least. Trump can’t ban EVs, wind farms and solar arrays.
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Good news everybody, climate change is over!
I thought a lot of climate initiatives took place at state, not federal level, though. Will these be affected by this nonsense?
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China’s CO2 emissions have now been ‘flat or falling’ for 21 months
Encouraging. Though I imagine the fall in cement production may be due to excessive speculative housing developments, which I understand have led to a slump in the Chinese property market and left a number of real estate and construction companies seriously under water. So may be an economically driven fall rather than the result of +ve climate policies.
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We are tricked by our brains
Yes, in my experience on these forums a lot of relativity eccentrics - I won't say cranks - and QM eccentrics too have an engineering background. I suspect it is because much of engineering is a sort of apotheosis of c.19th physics, seeming to achieve mastery over nature. This view was shaken by the advent of relativity and QM in the early c.20th, which told us a number of uncomfortably counterintuitive things about nature. (I was in fact taught 1st yr 6th form physics by a brilliant teacher who claimed to be agnostic about the existence of molecules! His degree was in engineering and he was great - at classical physics. But we got a different teacher in the 2nd year.) As Feynman said: "You don't like it? Go somewhere else! To another universe where the rules are simpler, philosophically more pleasing, more psychologically easy........I'm not going to fake it. I'm not going to tell you it's something like a ball bearing on a spring when it isn't. " Common sense is not enough.
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Epstein files reveal deeper ties to scientists than previously known.
From what I have read, it seems to me almost all were young women of 18+, with agency as adults. He did get done for underage girls of course but my impression is that there has been an extension, by the media, into implying most of these women were underage girls. But is that true? How many were actually under age?
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Epstein files reveal deeper ties to scientists than previously known.
That is quite funny.
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Epstein files reveal deeper ties to scientists than previously known.
I’m not sure that knowing Epstein socially even indicates creepiness. Seems just about everybody knew Epstein: he was a vigorous, ubiquitous socialite, by the sound of it. There doesn’t seem to be evidence that most of these people were involved with Epstein’s prostitutes.
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[Chem-Applied-Solutions] van’t Hoff factor i
Oh yes I don’t mean to suggest it’s wrong or anything like that. Just a bit weird - and in my opinion of doubtful utility to someone trying to learn the principles of chemistry at school level.
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[Chem-Applied-Solutions] van’t Hoff factor i
Interestingly, all the references to this "abnormal molar mass", including the one you cite, seem to be from Indian source material. I don't recall it from my own undergraduate studies (in the UK), there is no reference to it in my old Moore Physical Chemistry, nor it seems in the Chemistry Libretexts, or in Wikipedia or the other sources I habitually consult when revising chemistry.
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[Chem-Applied-Solutions] van’t Hoff factor i
I think it may be expressing this in terms of molar mass that is causing you the confusion. Think first of all in terms of the numbers of molecules, i.e. the number of moles of substance. Then i makes obvious sense as the ratio of the "effective" number of moles of particles (i.e. how the substance actually behaves in practice) to the "theoretical" number of moles of the substance (i.e. as it appears on paper from the chemical formula). I must say I think the idea of "abnormal molar mass" is a fairly unhelpful way of thinking about what that is going on. It could almost be designed to get you in a muddle. Nevertheless, see if the following explanation helps. For example if you consider a solution of a partially dissociated substance, its effective molarity would be less than the theoretical value. But the number of moles of a substance = mass of substance present/molar mass. So then an "effective" molarity < "theoretical" molarity could be interpreted to mean the "effective" molar mass > "theoretical" molar mass. This I think is what @KJW is getting at. Personally, I struggle to think of any situation in which the concept of an "abnormal molar mass" is at all useful. (But if other readers can think of a use for it, I'll be interested to learn). I much prefer to leave the molar mass as standard, and think of effective concentrations differing from that predicted by the (standard) molar mass.
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Windows at left, right, both ?
This is ridiculous. I attended 4 different schools over 13 years, the last 5 of which were at one in which pupils moved from classroom to classroom for each different subject. As far as I know this is common practice (and essential in science subjects, due to use of laboratories).
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[Chem-Applied] Vapour pressure of Pure Liquids A & B are 450 & 700mmHg respect. @350 K . Find comp. of liquid mix, total Vapour pressure is 600mmHg and Vapour phase composition
What does that mean?
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Madhouse Politics and Green Energy - Solutions please.
Good points. As I say, regardless of the comparative efficiencies I am sceptical about weights in old mine shafts etc., as I just don't see how enough weight can be shifted, compared to pumping water.
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Today I Learned
Today I was the “cantor” at Sunday mass for the Ave Regina Caelorum…..and learned we can call on a new guest soprano to help out from time to time, a pretty young woman by the name of Liberty, with a lovely (and clearly trained) voice. I had no idea this could be a girl’s name. I rather like it - and her - I must say.
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Everything is Foreign Relations to Trump
I share your fears. I am no longer confident the Supreme Court (or should that be Chicken?) is effective any longer. They have been due for weeks now to issue their judgement on whether or not Trump's tariffs are constitutional. I think they know damned well they are not, but are afraid to issue the judgement because of the damage that would do to Trump and his administration, both internationally and domestically (unwinding illegal tariffs would involve compensating the affected importers). In any case, the enforcing of court orders requires in the last resort the use of the US Marshals........which is an agency reporting to a certain Pam Bondi. So good luck with that, if and when a showdown with the courts arises. It also looks as if the role of ICE is gradually being expanded beyond its original remit of rounding up illegal immigrants. I note in particular the alarming presence of ICE to provide protection to Vance during his attendance at the Winter Olympics, in Italy. WTF? They seem to be morphing into a new arm of state security, outside the systems, controls - and training - of the normal security services and answerable to no one. They have already established a reputation for killing citizens with impunity. So the fear factor is being ramped up. What next? Brown shirts and diagonal leather straps across the chests?
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Madhouse Politics and Green Energy - Solutions please.
I have never understood how this can work at scale. It seems to me the mass of such weights cannot remotely compare with the mass of water that can be given extra gravitational potential energy by a couple of reversible pump/turbines in the space of a few hours. I think, though, I would expect the losses to be lower than with pumped storage, as there won't be losses to turbulence and "slippage" through the turbine. It will be just a matter of the efficiency of the electric motor/generator running in forward and reverse directions, which you also have in a pumped storage setup.
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Today I Learned
1960s special effects were pretty primitive.
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How should we use AI in medicine ?
Indeed. I don't know how diagnostic AI works but I imagine it may look for patterns in the data: X-ray pictures, blood analyses, physical examinations and so forth, and then provide the doctor with an assessment of probabilities of different conditions, or something like that. In this sad case, I imagine the doctor would then have had to make a decision to dismiss cancer from the list of possible conditions presented to him or her in black and white. This would be psychologically hard to do - and to justify in retrospect - if the AI came up with a probability of, say, over 20% for cancer. So maybe it might have prompted an intervention.
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How should we use AI in medicine ?
Hmm, I think this may be misunderstanding how diagnostic AI works. These are, to my understanding, not LLMs.
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Mechanism of hidden authoritarianism in Western countries
Merkel took that decision in 2011, in the wake of the Fukushima accident and long before Putin's invasion of Crimea. At the time, Germany had not yet given up Russia becoming a civilised trading partner. It is true that, even at the time, many other countries thought it a misguided over-reaction, given the climate change imperative (not to mention the absence of earthquake risk in Germany!). But there is no evidence of any "payment" to make this decision, so far as I am aware. This looks to me like just more of your (very Russian, trollish) obsession with conspiracies.
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What are you listening to right now?
Presumably because GDAE is how a violin is tuned, I seem to recall from when one of my brothers used to play.
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Today I Learned
Oh so you actually went to see it? We didn't. We just laughed at the posters for it on the Underground, on our way to and from school.
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Today I Learned
Haha I remember that one: "Krakatoa, East of Java". 🤪 I was at school at the time and we laughed at the idiocy.