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Extinction and concentration


HansLaroes

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Hello,

For a Chemistry project i have to determine the starch concentration of two solutions of which i only know the extinction (which i had of course determined using a colorimeter) using a calibration line plotted in excel derived from samples  of which the concentration + extinction was known. The problem is that i forgot to note the molarity of the starch-solution - from which i derived my samples -, even though i did note the mass concentration in g/L. Therefore i made a graph in excel with the concentration is in g/L and the extinction. Is this a valid relation? Or do i need to know the molarity of the starch-solution?

Best regards,

Hans

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Well since


[math]molarconcentration = \frac{{massconcentration}}{{molecularmass}}[/math]


and the molecular mass is a constant the form of your graph is OK,

but obviously for any result that needs to involve the the molar mass you will need that constant.

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Unless the starch molecule has a defined number of glucose monomers, I don't see how it can have a single molecular weight.  Polymers are not my strongest suit, but it might be possible to define an average molecular weight.

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2 hours ago, BabcockHall said:

Unless the starch molecule has a defined number of glucose monomers, I don't see how it can have a single molecular weight.  Polymers are not my strongest suit, but it might be possible to define an average molecular weight.

I presume there is a particular starch involved.

This may be for a pharmacy course and pharmacists often use average molecular weights.

And 'starch' is a common constituent of pills various.

 

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