hermanntrude Posted September 9, 2009 Share Posted September 9, 2009 OK so today I tried a new demo and i'm very excited. Before I start I should remind everyone that this cannot be attempted outside of a proper chemistry laboratory. Bromine is extremely hazardous and hard to safely dispose of and handle and the same is true of potassium. Anyway, what I did was this: I took a long piece of metal (steel, i think), and bent the end downwards by 90°, so that the end part was just long enough to reach the bottom of a large beaker. To the end I attached a piece of copper wire. Into the large beaker I placed a small beaker with enough bromine in it to cover the bottom. To the top of the bent part of the metal stick I attached a DVD so that when the stick was fully inserted into the beaker, the DVD would cover the opening at the top of the beaker. I then attached a very small (perhaps 2-3mm diameter) piece of potassium metal (washed in hexane and dried in air) to the wire at the tip of the metal stick. I then placed an explosion guard over the front of the beaker and lowered the sash of the fume hood as far as possible. Then I lowered the potassium into the bromine. A small explosion ensued and copious quantities of white smoke floated gently away into the fume hood. it was awesome. Video to follow at a later date. Link to comment Share on other sites More sharing options...
John Cuthber Posted September 9, 2009 Share Posted September 9, 2009 I look forward to the video. However, just in case anyone ever looks up this thread because they want some KBr and they have some bromine, here's a less "exciting" way to do it. (I have a rough idea how likely that is, but this post didn't cost much) Pass bromine over heated iron filings to produce a mixture of iron bromides. (or dissolve the Br2 in a suitable solvent and react it with iron.) Leach the Fe bromides into water and add potassium hydroxide or carbonate until all the iron is precipitated. filter off the Fe oxide/hydroxide/carbonate then evaporate down the solution to get KBr. Link to comment Share on other sites More sharing options...
hermanntrude Posted September 9, 2009 Author Share Posted September 9, 2009 nice method. Of course, KBr is dirt cheap anyway :0) Link to comment Share on other sites More sharing options...
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