Jump to content

Organic Chemistry -- liquid-liquid extractions

Featured Replies

I have a mixture of:

--benzoic acid [C6H5COOH]

--phenol [C6H5OH]

--hydroquinone [C6H4(OH)2]

--dimethylether [H3COCH3]

 

I understand that I can add sodium bicarbonate to get two layers, the aqueous layer containing C6H5COONa. To the remaining ether layer, I can add NaOH to get C6H5ONa and water in the aqueous layer. The question I'm working on now asks what would happen if I added the NaOH before I added the NaHCO3.

 

I understand that if I added the NaOH first, it would react with both the phenol and the benzoic acid (right?). However, would the sodium bicarbonate react with the hydroquinone? I don't think it will because hydroquinone is too weak of an acid. Is this correct?

 

Any input would be appreciated. Thank you. :)

HQ is "activated" in a basic soln making it a very potent scavenger of oxidisers, which includes Oxygen in the air.

Archived

This topic is now archived and is closed to further replies.

Important Information

We have placed cookies on your device to help make this website better. You can adjust your cookie settings, otherwise we'll assume you're okay to continue.

Configure browser push notifications

Chrome (Android)
  1. Tap the lock icon next to the address bar.
  2. Tap Permissions → Notifications.
  3. Adjust your preference.
Chrome (Desktop)
  1. Click the padlock icon in the address bar.
  2. Select Site settings.
  3. Find Notifications and adjust your preference.