Jump to content

Chem quiz

Featured Replies

Thought i would do a chem quiz (feeling nerdy):

 

50.00 mL of a solution of nickel bromide was treated with an excess of dimethylglyoxime solution. The precipitated Ni(DMG)2 was filtered off; 0.3177g was obtained. Calculate the concentration (molarity), of the nickel bromide solution.

 

I will say when i see the correct answer.

Molecular weight of [Ni(dmg)2] = 232.77

 

Concentration = 0.0273 moles per litre.

I don't have those chemicals/elements memorized anymore, nor do I have a table of them.

:-(

You mean a periodic table? Not that hard to come by surely!

  • Author

Mr Ni(C4H7N2O2)2 = 288.93 g mol-1

 

Amount Ni(dmg)2 = mass/molar mass = 0.3177 g/288.93 g mol-1

=1.100 x 10-3 mol Ni(dmg)2

 

1 mol NiBr2 gives 1 mol Ni(dmg)2 so amount NiBr2 = 1.100 x 10-3 mol

 

Concentration of NiBr2 = amount/volume = 1.100 x 10-3 mol/50.00 x 10-3 L

= 0.02199 M

 

NB The final answer to 4 sf is 0.02199 M not 0.02200 M, because although I

have written the intermediate result as 1.100 x 10-3 mol, I have not actually rounded it to 4sf at this point. The figure on the calculator is 1.09957 x 10-3, and I have used this figure in the subsequent calculation and rounded off only at the last step. In this case it doesn't make a lot of difference, but in highly precise analytical work it may do.

 

very close greg

Archived

This topic is now archived and is closed to further replies.

Important Information

We have placed cookies on your device to help make this website better. You can adjust your cookie settings, otherwise we'll assume you're okay to continue.

Configure browser push notifications

Chrome (Android)
  1. Tap the lock icon next to the address bar.
  2. Tap Permissions → Notifications.
  3. Adjust your preference.
Chrome (Desktop)
  1. Click the padlock icon in the address bar.
  2. Select Site settings.
  3. Find Notifications and adjust your preference.