PoochGroup Posted December 11, 2015 Share Posted December 11, 2015 The first step is the RDS since the LG leaving generates a highly unstable carbocation. My question is whether everything else in the diagram is correct (such as my delta H calculation and relative values for the other steps). http://i.imgur.com/4qHmnyo.png Thanks Link to comment Share on other sites More sharing options...
hypervalent_iodine Posted December 11, 2015 Share Posted December 11, 2015 The first step is the RDS since the LG leaving generates a highly unstable carbocation. My question is whether everything else in the diagram is correct (such as my delta H calculation and relative values for the other steps). http://i.imgur.com/4qHmnyo.png Thanks Well, it's not highly unstable, just less stable than the benzylic position. The plot looks fine otherwise. Personally, I would draw the lines so flat at the product and reactant ends and I'd make the ascent and descent more sloped, but this is a very minor point and one you'd not get marked down for ignoring. Link to comment Share on other sites More sharing options...
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