chehemi123 Posted December 4, 2012 Share Posted December 4, 2012 Hey guys... i´m looking for an orbital energy diagram of soluble Berlin Blue:K[FeIIIFeII(CN)6] I don't know how to combine the two diagrams of the hexacyanoferrates [Fe(CN)6]4- and [Fe(CN)6]3+...so that we have K[Fe(III)Fe(II)(CN6)]. Can you have a look at my idea? diagrams.pdf Link to comment Share on other sites More sharing options...
mississippichem Posted December 4, 2012 Share Posted December 4, 2012 Your MO diagrams for the two hexacyano-iron complexes are correct except for not showing the occupied pi states on the cyano ligands . I honestly have no idea how you would construct an MO diagram for the whole mixed oxidation state complex. What do you expect the nature of the Fe-Fe bond to be? Link to comment Share on other sites More sharing options...
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