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HF + NaCl is a buffer?

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You need to look up what a buffer is.

 

 

 

And how can I calculate the pH of this solution

 

'Henderson-Hasslebach' google it.

What do you know about calculating PH? Perhaps you may not need to know about Henderson-Hasslebach equation to calculate the PH of the solution you're referring. You just need acreative way of finding the remaining Hydrogen ion from the reaction of the two.

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