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Catalytic Hydrogenation and stability

Khyati
in Organic Chemistry

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1)Why can the use of high temperatures in the catalytic hydrogenation of alkenes to alkanes be self-defeating ?

2)We know that if the substituent is present at the equatorial position in cyclohexane then that compound is more stable, then why all trans-1,2,3,4,5,6-Hexaisopropylcyclohexane is a stable molecule in which all isopropyl groups are axial ?

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