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Electron transport chain and DCPIP!

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Got a few questions which are really confusing me;

 

Which of the electron transport chain complexes donates electrons to DCPIP and which complex accepts electrons?

Why would cyanide increase the rate of DCPIP reduction?

Lastly how would i estimate the redox potential of DCPIP, what information would i need to do so?

 

Any help would be grrrrreat!

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