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bond orders

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What are the bond orders in H2, H2+, and H2- respectively based on molecular theory

 

thanx guyz

Bond order is equal to (the number of electrons in bonding orbitals - the number of electrons in antibonding orbitals)/2. In a diatomic hydrogen molecule, there is one bonding orbital (which holds two electrons) and one antibonding orbital (which holds an additional two electrons). Because the bonding orbital has a lower energy, you fill that one up first before electrons are added into the antibonding orbital.

 

In H2, each hydrogen contributes two electrons which both go into the bonding orbital. The bond order is 1.

 

H2+ is lacking an electron, so its one electron goes into the bonding orbital. The bond order is 1/2.

 

H2- has an extra electron. The first two electrons fill the bonding orbital, so the third goes into the antibonding orbital. The bond order is therefore 1/2 [(2-1)/2]

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