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Schiff base metal complex

Pharmacist

By Pharmacist,
in Inorganic Chemistry

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Pharmacist

Pharmacist 0

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Hello

I am confused most papers says schiff base complexation with metals resulting in lower shift in Ir spectrum of azomethine group.
As far as I know decreasing e density leads to increase the frequency vibration.
However after intense inspections, I found two papers says it causes to increase the freq.
 
Is it possible for both??
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