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Caesium auride


EwenM

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I'd like some information about the strange ionic compound caesium auride to complete a Born-Haber cycle about its formation. I thought it would make a change from NaCl!

 

Does anyone know its enthalpy of formation or its lattice enthalpy? I've looked in every text we have and scoured the web, but without luck.

 

For the curious, Here's what I do know:

 

CsAu is ionic, with the Au- anion in a lattice that closely resemble CsCl. The Cs-Au distance is 369 pm. Atomisation enthalpies are 78.7 kJ/mol for Cs and 369 kJ/mol for Au. The ionisiation energy of Cs is 375.7 kJ/mol and the electron affinitiy of Au is -222.8 kJ/mol.

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